Research
Research projects

Research Projects at the Institute

Quantenchemie

  • Junior Research Group BMBF NanoMatFutur
    MÜKoN - Materials from Superstructures of Taylor-Made Colloidal Nanocrystal Building Blocks
    Leaders: Dr. Nadja-Carola Bigall
    Year: 2013
    Lifespan: 4 years
  • Colloid chemically produced strongly doped (degenerate) semiconducting and oxidic nanocrystals with localized surface plasmon resonances (DFG research project)
    The occurrence of localized surface plasmon resonances (LSPRs) is now a well-known and well-researched phenomenon in noble metal nanoparticles. Due to this fascinating physical effect, there is a variety of research and application areas such as nanooptics, fluorescence amplification, surface enhanced Raman spectroscopy (SERS), plasmon-based sensor technology and much more. However, so far there are hardly any alternatives to the noble metal materials in the field of nanoparticles containing LSPR, which limits the applicability to special areas of the spectrum and is associated with high material costs. To address this deficiency, the project aims at the synthesis and characterization of a new class of plasmon nanocrystals, i.e. highly doped metal oxide and semiconductor nanoparticles with plasmonic properties. For this purpose, synthesis strategies for strongly self-doped semiconductor nanomaterials such as Cu(2-x)Se are developed, as well as synthesis strategies for strongly doped nanocrystals of zinc oxide and tin oxide. Furthermore, for these new materials it is expected that the control of the chemical and dielectric environment of the nanoparticles is critical to change or stabilize the plasmonic properties of the nanocrystals. Therefore, a fine tuning of LSPR frequencies will be performed by the development and application of post-synthetic processing steps such as shell growth or ligand exchange, and finally, this new type of plasmonic nanoparticles will be investigated with respect to the possibility of replacing or complementing the current gold nanoparticles (or other precious metal nanoparticles) in LSPR-based sensory applications. A positive result would lead to an alternative (or complementary) class of plasmon nanoparticles and thus to a new nanoparticle family for applications in plasmon-based sensor systems.
    Leaders: PD Dr. Dirk Dorfs, Prof. Dr. Wolfgang Parak
    Team: Dorfs Group
    Year: 2013
    Sponsors: DFG Deutsche Forschungsgemeinschaft
  • Hannover School for Nanotechnology: Interdisciplinary Approaches for Smallest Sensors
    Subproject assembly architectures of (semiconducting, superparamagnetic, plasmonic, etc.) nanocrystals as part of the Graduate School of the Lower Saxony PhD Program of the Lower Saxony Ministry for Science and Culture (MWK)
    Year: 2016
    Lifespan: 3 years
  • Multicomponent Nanoparticle Gels for Photovoltaic Applications
    Funded by the German Academic Exchange Service (DAAD) in the context of the announcement DAAD PPP with India (with the DST) for a cooperation with the research group of Prof. Sameer Sapra at the IIT Delhi
    Year: 2016
    Lifespan: 2 years
  • Hollow and Concave Colloidal Plasmonic Nanoparticles as Size and Shape Selective Sensors on the Nanometerscale
    In the framework of this project, colloid chemically synthesized plasmonic nanoparticles shall be investigated with respect to their potential as size and shape selective sensors on the nanometerscale in liquid phase. For this purpose a variety of different plasmonic nanoparticles will be synthesized. Already this pure synthesis part of the project will go beyond the state of the art in nanoparticle synthesis. Apart from “normal” plasmonic particles from noble metals also plasmonic particles from highly doped (degenerately doped) semiconductor or oxide materials with localized surface plasmon resonances tunable in the near infrared part of the spectrum shall be synthesized and shall be compared with the classic metallic nanoparticles with respect to their sensory properties. The plasmonic particles can detect an analyte either via changes of the dielectric constant of the surrounding or via other, specific interactions with the analyte. With respect to the latter point, especially plasmonic particles with concave or cylindrical voids at the particle surface shall be synthesized, which can show size and shape selective interactions with different analytes (see also scheme for e.g. key lock like interactions) which finally can easily be detected by a change of the resonance frequency of the localized surface plasmon resonance of these particles.
    Leaders: PD Dr. Dirk Dorfs, Prof Dr. Detlef Bahnemann
    Team: Arbeitsgruppe Dorfs
    Year: 2016
    Sponsors: Hannover School of Nanotechnology
  • Preparation of heterogels from metal and metal oxide nanocrystals by means of cryogelation methods for use in electrocatalysis
    Research grant from the Deutsche Forschungsgemeinschaft (DFG) for the investigation of new porous self-supporting gels made of metal/metal oxide (M/MO) mixed systems by means of cryogelation with respect to their suitability as electrocatalysts
    Leaders: Prof. Dr. rer. nat. Nadja-Carola Bigall
    Year: 2017
    Sponsors: DFG
    Lifespan: 3 years
  • Multicomponent Aerogels with Tailored Nano-, Micro- & Macrostructure (MAEROSTRUC)
    As part of the ERC Starting Grant, multicomponent nanoparticle aerogels are synthesized by nano-, micro-, and macrostructuring to produce new physico-chemical properties that neither the nanoparticles nor the associated macroscopic solid-state materials possess
    Leaders: Prof. Dr. rer. nat. Nadja-Carola Bigall
    Year: 2017
    Sponsors: European Research Council (ERC)
    Lifespan: 5 years
  • Plasmonic nanocrystals and multicomponent nanocrystals for activation of chemical reactions by ultrashort temperature pulses
    This project aims to investigate the effects of ultrafast heated plasmonic nanoparticles in colloidal solution on their environment and in particular on chemical reactions occurring in their environment. Plasmonic nanoparticles can be heated extremely quick and strongly by ultrashort (nanoseconds or picoseconds) laser pulses. Plasmonic nanoparticles have some unique properties: Their extinction coefficients are extremely high and even with the most intense laser irradiation there is hardly any fading effect during the laser pulse compared to other materials. In addition, the spectral position of the plasmon resonance can be adjusted practically arbitrarily by material selection as well as size and shape of the particles. As a consequence, such plasmon nanoparticles can even be heated by single picosecond laser pulses by more than 1000°C; initially without their environment being heated. In this project, the effects of such extremely short and extremely localized temperature peaks on the chemical reactions of reactants, which are also present in the colloidal solutions of such nanoparticles, will be investigated. suitable plasmonic nanoparticles will first be produced, whereby degenerate doped semiconductor particles with plasmon resonances in the near infrared spectral range will be produced in addition to classical noble metal nanoparticles. Multicomponent particles are also produced, which consist of a plasmonic part for rapid heating under laser irradiation and another part of a catalytically active material. The heat generated by the laser pulse in the plasmonic particle is transferred to the catalytically active part and a chemical reaction takes place on its surface. Various simple chemical reactions, which either take place directly on the surface of the rapidly heatable nanoparticles or in their immediate environment in solution, are investigated. The conditions are chosen so that macroscopically there is practically no heating of the solution and only extremely short and extremely localized temperature peaks occur. The results of these investigations will allow conclusions to be drawn about how heat conduction in solutions takes place on extremely short time scales and over very short distances, whereby such scenarios are also of particular interest in which the particle temperature directly after the temperature pulse is significantly above the boiling temperature of the solvent, since such scenarios cannot be realized on a macroscopic scale.
    Leaders: PD Dr. Dirk Dorfs, Prof. Dr. Carsten Reinhard
    Team: Dorfs Group
    Year: 2017
    Sponsors: DFG Deutsche Forschungsgemeinschaft
    Lifespan: 3 years
  • Cluster of Excellence PhoenixD - Photonics, Optics, Engineering, Innovation across Disciplines
    PhoenixD is a broad and interdisciplinary initiative to redefine the design and manufacture of precision optics. It is based on the interweaving of optical design, optical simulation and modern production methods into a single, integrated platform designed to create and produce individual and highly functional precision optical systems.
    Leaders: Prof. Dr. Uwe Morgner, Prof. Dr.-Ing. Ludger Overmeyer, Prof. Dr.-Ing. Wolfgang Kowalsky
    Year: 2019
    Sponsors: DFG
    Lifespan: 7 Jahre
  • Novel Water Treatment Technologies; from Nanofiltration to Electrolysis
    The efficient cleansing of waste water is an important procedure relevant for all sorts of communities. This could be on the ISS, where water is valuable due to transportation costs and must be recycled while available electricity is no problem. This situation can also occur in arid regions on earth. In fact, two billion people have no access to clean toilets. This is the point where the Bill & Melinda Gates foundation started a larger project. The aim propagated by Bill Gates is to convert waste water within five minutes into drinkable water. Side products of this process should have economical value, for example as fertilizer or as fuel. Generally, sewage treatment consists in four stages after a pretreatment which removes large objects. The first step is sedimentation which helps only moderately if the process is supposed to be finished within five minutes. The second step is a bio treatment which destroys effectively potentially hazardous bio systems. Next, disinfection with compounds like formaldehyde is supposed to destroy residual toxins. In some countries, amongst them Germany, a fourth step is added, namely a chemo- physical treatment, supposed to destroy or filter the remaining chemical compounds like for example pharmaceuticals or dyes. We will focus on the investigation of novel approaches for this fourth step.
    Leaders: Prof. Frank
    Team: AG Frank
    Year: 2020
    Sponsors: DFG Deutsche Forschungsgemeinschaft
    Lifespan: 1 Jahr

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